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59 -- To improve computer memory, catalysts, ceramic/metal seals and nanodevices.

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04-255Federal

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Sandia National Laboratories is offering a patent-pending technology for engineering improved interfaces between metals and metal oxides, aiming to partner with industrial companies interested in licensing or cooperative development. This novel method eliminates the need for high-temperature brazing in joining metals to oxides, enabling the creation of flat, nanometer-thin crystalline and ferromagnetic metal layers on oxide surfaces. The improved metal-oxide interface demonstrates enhanced strength, stability, and uniformity, which translates to lower material costs and reduced electrical energy requirements for producing faster magnetic effects, particularly beneficial for advancing magnetic random access memory (MRAM) technology. Beyond computer memory improvements, the technique holds promise for producing more efficient and cost-effective catalysts, stronger ceramic/metal seals, and innovative nanodevices. The method involves either fully hydroxylating and purifying the oxide surface to chemically bond oxidized metal atoms strongly through ionic bonds, acting as anchors for further metal growth and resulting in high crystallinity despite lattice mismatches, or introducing a sub-monolayer of negatively charged species on the oxide surface to enhance metal adhesion by promoting layer-by-layer growth. Both approaches help control the growth, adhesion, and interfacial strength between metal and oxide layers, supported by experimental and theoretical findings. Interested partners are invited to submit a statement of interest within 30 days, addressing the intended markets for the technology, with contact information provided for further communication.

General Info

Sandia offers patent-pending metal-oxide interface technology improving strength, stability, and MRAM efficiency.

Agency

N/A

NAICS

334119 - Other Computer Peripheral Equipment Manufacturing

Place of Performance

Not specified

Set-Aside

NONE

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0

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Full Description

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Sandia National Laboratories is seekingindustrial partners interested in a patent-pending method for engineering interfaces between metals and the oxides of metals. Simple method may improve computer memory, catalysts, ceramic/metal seals, and nanodevices Sandia National Laboratories (www.sandia.gov) is seeking industrial partners interested in licensing a patent-pending method for engineering interfaces between metals and the oxides of metals. The allowed patent application is awaiting issuance. The method eliminates the high-temperature brazing step from the joining process of metals to metal oxides and has several potential applications. For instance, by improving magnetic random access memories, this method helps next generation computers boot up instantly and helps retain their entire memories after power interruptions. This technique enables the deposition of flat, nanometer-thin crystalline and ferromagnetic metallic layers on similarly thin oxide layers. The strength, stability and uniformity of the oxide-metal interface reduces material cost and requires less electricity to produce more rapid magnetic effects for the computer memory. In addition, this inexpensive technique may produce better, less expensive (more highly dispersed but stable) catalysts for chemical reactions, better ceramic/metal seals, and lead to improved nanodevices. Sandia is interested in partnering with companies for future applications of this technology via licensing or cooperative development agreements. Interested parties should mail or fax a statement of interest to Colleen Kearney within 30 days from the date this announcement is published at: Sandia National Laboratories, MS 0115, P.O. Box 5800, Albuquerque, New Mexico 87185-0115, Fax: +1 (555) 000-0000. Please indicate the date and title of this notice and the markets in which you would like to apply the technology. Patent Abstract A method of controlling the growth and interfacial strength of a metal deposited on an oxide layer. a) By first fully hydroxylating the oxide surface and then cleaning it of impurities, deposited metals can produce a chemical reaction that oxidizes a fraction of the metal atoms and reduces hydrogen. The oxidized metal atoms are incorporated into the oxide surface and bind strongly to it by ionic bonds. However, these metal atoms also bind strongly to metallic metal above and serve as - anchors to bind more metal. At sufficient concentration, laminar growth is achieved and crystallinity is observed at only about 6 metal atomic layers, in spite of large lattice mismatches. These findings are supported by both experimental and theoretical results. Or b) A method of controlling the wetting characteristics and increasing the adhesion between a metal and an oxide layer. By introducing or producing a sub-monolayer of negatively-charged species to the surface of an oxide layer, layer-by-layer growth of metal deposited onto the oxide surface is promoted, increasing the adhesion strength of the metal-oxide interface. The negatively-charged species can either be deposited onto the oxide surface or a compound can be deposited that dissociates on, or reacts with, the surface to form the negatively-charged species. The deposited metal atoms can thereby bond laterally to the negatively-charged species as well as vertically to the oxide surface as well as react with the negatively charged species, be oxidized, and incorporated on or into the surface of the oxide. Point of Contact Colleen Kearney, Administration, Phone: +1 (555) 000-0000, Fax: +1 (555) 000-0000, E-mail: contact@example.gov

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